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Assistant Professor 617-552-8450 Education
Research Interests Electron Structure in the light actinides: My current research using x-ray and electron photoemission spectroscopy at Los Alamos National Laboratory (LANL) focuses on exploring the electron structure of the valence (d and f ) electrons in single crystal Uranium. Current band structure model calculations such as WIEN2K can not fully account for the actinide valence electron behaviors. By comparing experimental data and model calculations, we endeavor to create a new band model that will better predict electron valence behaviors across the actinide series. Building a Laboratory: My experiment laboratory, currently under development/construction in Higgins 130D, will enable low-temperature ~ 2 – 350 K resistance, dilatometry and resonant ultrasound (RUS) measurements under magnetic fields of 9T. Magnetic field and low temperatures will be attained by utilizing a Quantum Design Evercool PPMS. RUS measurements are planned using a Quasar International RUSpec apparatus adapted for high (2000 K) and low temperature (2 -350 K) measurements. The ultrasound technique utilizes high frequency sound and monitors mechanical response to determine fundamental thermodynamic properties (elastic moduli) of a material characteristics. Future Research: My research plans are directed at avalanche transitions (see: Perkovic, et al., PRL 75, 4528, 1995) probed by ultrasonic techniques in magnetic fields such as: ultrasonic attenuation (see: Stenger, et al., PRB 57, 2735, 1998), pulse-echo (Keck, et al., PR 185, 1083, 1969), and resonant ultrasound spectroscopy, (Migliori, et al., PRL 64 , 2458, 1990). In particular, RUS is a technique by which the complete elastic tensor is determined from the spectrum of the mechanical resonances of an object. A numerical procedure is used to generate the expected frequency spectrum for a given set of elastic moduli, cij, and comparison with data of known crystal symmetries and orientations provides the matrix cij consistent with the measurement. My future research will focus on two specific classes of multiferroic materials: magnetoelectrics and thermoelastics. These two classes are related in that they undergo structural phase transformations and both unit cell strain and intra-unit cell distortions (shuffles) are essential for understanding materials behavior. Whereas thermoelastics provide a deeper insight into the role of strain and shuffle modes, multiferroics underline the interplay between spin and charge. For example, the series RMnO3, (where: R = Tb, Dy, Gd, Ho) has strong magnetoelectric coupling and exhibits giant magnetoelectric and capacitive effects. It is possible to search for new magnetoelectric materials by focusing on previously identified insulating magnetic systems, especially compounds with higher temperature transitions that may be integrated into potential device applications. The thermoelastic alloys (transition based -phase binary alloys such as AuZn, AuCd, AgZn) display signatures of the interplay of strains and shuffles with electronic properties and the strength of this coupling has recently been determined (see: Goddard et. al., PRL 94, 116401, 2005). Thus, a mechanism for the role of conduction electrons through a metastable transition is understood, particularly in the presence of high magnetic fields. As part of this project I will investigate new thermoelastic alloys that have enhanced properties such as deformability, greater recoverability of transformation strain, and transition temperature, all of which are controlled by the conduction electrons in external fields. Publications
Invited Talks 2006 University of Barcelona, Spain, Topic: ARPES on U and the Pseudogap in Ni2MnGa, 03 June 2006. 2006 Georgetown University Science Lecture Series, Topic: LEED, ARPES and WIEN2K Band Structure Calculation of a - Uranium (001) 31 January 2006, Georgetown University, Reiss Science Building. 2005 LANL Workshop on Correlated Electron Effects for Anomalous Properties of Elemental Actinides (May 23-25, 2005) Los Alamos, NM Topic: ARPES on Single Crystal Uranium and Other New Results (Workshop Organizers: K. B. Blagoev, B. Mihaila, C.P. Opeil & J. L. Smith). 2004 CalCon - The 59th Calorimetry Conference (June 27 - July 1, 2004) Santa Fe, NM,
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